= 1.five 10-5 m2 s-1 was identified through chronoamperometric data remedy in [29] under
= 1.five 10-5 m2 s-1 was discovered throughout chronoamperometric data therapy in [29] below the assumption of purely diffusion development manage. Important discrepancies are clearly visible each inside the cathode and in the anodic region (dotted and Methyl jasmonate Biological Activity dashed lines).erials 2021, 14, x FOR PEER REVIEWMaterials 2021, 14, 6330 Supplies 2021, 14, x FOR PEER REVIEW9 of 12 9 of9 ofFigure Comparison of simulation benefits for diffusion development handle at at D = 1.5 10-5 m2 1-1 Figure 4.four. Comparison of simulation benefits for diffusion development handle D = 1.5 10-5 m2 s-s 2 -2 (dottedline) and mixed growth manage at D = 1.72 10-5-5 m-1,si-1 , six.32 10-2 A10-2 A cm-= and (dotted line) and mixed development manage at D = 1.72 ten m s 2 0 = i0 = 6.32 cm and 2 0.128 (strong line) with experimental CV (dashed line) [29]. = 0.128 (solid line) with experimental CV (dashed line) [29].Figure 4. Comparison the simulation enables SBP-3264 Cancer tracing the modify within the manage at D = 1.five 10-5 m2 Furthermore, of a nonlinear results for diffusion development size and development deterNow let us make calculation fitting by the Levenberg arquardt algorithm to regime 2 -1 (dotted line) nucleus applying the adjust in theD =instead 10-5(Figure 5).0 The maximum calculated = 0.1 1.72 of Equation i = six.32 10-2 A cm-2 and of your and mixed development manage at overpotential m s ,(19), i.e., contemplating mixed mine D, i0 , and during formula (7) (or (18)) (strong growth control. In about 126we(dashed line) [29]. line) with experimental CV can achievenot contradict thebetween the experimental and nucleus radius is this way, nm. This does very good agreement AFM observations [29], which] tude greater than the contribution of diffusion limitations ( Rd = [2 rzec 0 D-1 ) as much as r magnitude greater than the contribution of diffusion limitations (Rd = [2rzec0 D ] ) up nm. The 5 nm. The Rct and R values will come to be equal 64 64 mV (triangle in Figure five). Furth to r Rct and Rd values will turn into equal at at mV (triangle in Figure 5). d the diffusionthe diffusion contribution will prevail the transition to for the anode area. As the n Additional, contribution will prevail until until the transition the anode region. As cleus the nucleus dissolves, theof diffusion limitations will steadily reduce, along with the d dissolves, the effect effect of diffusion limitations will gradually reduce, as well as the discharge limitations will raise. charge limitations will improve.show that the nucleus can slightly extend beyond The top agreement was obtained simulated curves (solid and dashed lines in Figure 4). the Pt nanoelectrode. Simulations demonstrate that m s-1 , i = 6.32 10-2 A the 2 , adjust in As a result, the proposed at addition, the the 2charge0 transfer controls cm-growth = 0.128. nucleus. For development In D = 1.72 10-5 calculation makes it possible for tracing theand of smallthe size andthis CV, regim two the contribution of far more limitations ( overpotential f ( – p )]-1 ) The maximum calculat of themodel can in the course of akineticaccurate interpretation i0 exp (Figure five).is an order of magninucleus supply the modify inside the Rct = [2r of your experimental benefits. -1 Moreover, the calculation allows tracing the modify in R growth regime tude greater about 126 nm. This will not limitations thedsize andobservations of nucleus radius is than the contribution of diffusioncontradict (the = [2rzec0 D] ) as much as r 5 whi AFM [29], the nucleusctduringdthe adjust inside the overpotential(Figure 5). The maximum calculated nm. The R nucleus can will turn out to be equal atbeyond the Pt nanoe.
